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Uranium

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Uranium

Uranium is a chemical element; it has symbol U and atomic number 92. It is a silvery-grey metal in the actinide series of the periodic table. A uranium atom has 92 protons and 92 electrons, of which 6 are valence electrons. Uranium radioactively decays, usually by emitting an alpha particle. The half-life of this decay varies between 159,200 and 4.5 billion years for different isotopes, making them useful for dating the age of the Earth. The most common isotopes in natural uranium are uranium-238 (which has 146 neutrons and accounts for over 99% of uranium on Earth) and uranium-235 (which has 143 neutrons). Uranium has the highest atomic weight of the primordially occurring elements. Its density is about 70% higher than that of lead and slightly lower than that of gold or tungsten. It occurs naturally in low concentrations of a few parts per million in soil, rock and water, and is commercially extracted from uranium-bearing minerals such as uraninite. Many contemporary uses of uranium exploit its unique nuclear properties. Uranium is used in nuclear power plants and nuclear weapons because it is the only naturally occurring element with a fissile isotope – uranium-235 – present in non-trace amounts. However, because of the low abundance of uranium-235 in natural uranium (which is overwhelmingly uranium-238), uranium needs to undergo enrichment so that enough uranium-235 is present. Uranium-238 is fissionable by fast neutrons and is fertile, meaning it can be transmuted to fissile plutonium-239 in a nuclear reactor. Another fissile isotope, uranium-233, can be produced from natural thorium and is studied for future industrial use in nuclear technology. Uranium-238 has a small probability for spontaneous fission or even induced fission with fast neutrons; uranium-235, and to a lesser degree uranium-233, have a much higher fission cross-section for slow neutrons. In sufficient concentration, these isotopes maintain a sustained nuclear chain reaction. This generates the heat in nuclear power reactors and produces the fissile material for nuclear weapons. The primary civilian use for uranium harnesses the heat energy to produce electricity. Depleted uranium (238U) is used in kinetic energy penetrators and armor plating. The 1789 discovery of uranium in the mineral pitchblende is credited to Martin Heinrich Klaproth, who named the new element after the recently discovered planet Uranus. Eugène-Melchior Péligot was the first person to isolate the metal, and its radioactive properties were discovered in 1896 by Henri Becquerel. Research by Otto Hahn, Lise Meitner, Enrico Fermi and others, such as J. Robert Oppenheimer starting in 1934 led to its use as a fuel in the nuclear power industry and in Little Boy, the first nuclear weapon used in war. An ensuing arms race during the Cold War between the United States and the Soviet Union produced tens of thousands of nuclear weapons that used uranium metal and uranium-derived plutonium-239. Dismantling of these weapons and related nuclear facilities is carried out within various nuclear disarmament programs and costs billions of dollars. Weapon-grade uranium obtained from nuclear weapons is diluted with uranium-238 and reused as fuel for nuclear reactors. Spent nuclear fuel forms radioactive waste, which mostly consists of uranium-238 and poses a significant health threat and environmental impact.

Infobox

Pronunciation
/jʊˈreɪniəm/ ⓘ (yuu-RAY-nee-əm)
Appearance
silvery gray metallic; corrodes to a spalling black oxide coat in air
Atomic number (Z)
92
Group
f-block groups (no number)
Period
period 7
Block
f-block
Electron configuration
[Rn] 5f3 6d1 7s2
Electrons per shell
2, 8, 18, 32, 21, 9, 2
Phase at STP
solid
Melting point
1405.3 K (1132.2 °C, 2070 °F)
Boiling point
4404 K (4131 °C, 7468 °F)
Density (at 20° C)
19.050 g/cm3
when liquid (at m.p.)
17.3 g/cm3
Heat of fusion
9.14 kJ/mol
Heat of vaporization
417.1 kJ/mol
Molar heat capacity
27.665 J/(mol·K)
P (Pa)
Vapor pressure P (Pa) 1 10 100 1 k 10 k 100 k at T (K) 2325 2564 2859 3234 3727 4402
at T (K)
2325
Oxidation states
common: 6 −1, 1, 2, 3, 4, 5
Electronegativity
Pauling scale: 1.38
Ionization energies
1st: 597.6 kJ/mol 2nd: 1420 kJ/mol
Atomic radius
empirical: 156 pm
Covalent radius
196±7 pm
Van der Waals radius
186 pm
Natural occurrence
primordial
Crystal structure
orthorhombic (oS4)
Lattice constants
a = 285.35 pmb = 586.97 pmc = 495.52 pm (at 20 °C)
Thermal expansion
15.46×10−6/K (at 20 °C)[a]
Thermal conductivity
27.5 W/(m⋅K)
Electrical resistivity
0.280 µΩ⋅m (at 0 °C)
Magnetic ordering
paramagnetic
Young's modulus
208 GPa
Shear modulus
111 GPa
Bulk modulus
100 GPa
Speed of sound thin rod
3155 m/s (at 20 °C)
Poisson ratio
0.23
Vickers hardness
1960–2500 MPa
Brinell hardness
2350–3850 MPa
CAS Number
7440-61-1
Naming
after planet Uranus, itself named after Greek god of the sky Uranus
Discovery
Martin Heinrich Klaproth (1789)
First isolation
Eugène-Melchior Péligot (1841)
Main isotopes
mw- body Main isotopes Decay Isotope abun­dance half-life (t1/2) mode pro­duct 232U synth 68.9 y α 228Th SF – 233U trace 1.592×105 y α 229Th SF – 234U 0.005% 2.455×105 y α 230Th SF – 235U 0.720% 7.04×108 y α 231Th SF – 236U trace 2.342×107 y α 232Th SF – 238U 99.3% 4.463×109 y α 234Th SF – β−β− 238Pu
232U
synth
233U
trace
234U
0.005%
235U
0.720%
236U
trace
238U
99.3%

Tables

at T (K)
at T (K)
P (Pa)
at T (K)
1
2325
10
2564
100
2859
1 k
3234
10 k
3727
100 k
4402
P (Pa)
1
10
100
1 k
10 k
100 k
at T (K)
2325
2564
2859
3234
3727
4402
mw- Isotope
mw- Isotope
Main isotopes
mw- Isotope
Main isotopes
abun­dance
Main isotopes
half-life (t1/2)
Decay
mode
Decay
pro­duct
232U
232U
Main isotopes
232U
Main isotopes
synth
Main isotopes
68.9 y
Decay
α
Decay
228Th
SF
SF
Main isotopes
SF
Main isotopes
233U
233U
Main isotopes
233U
Main isotopes
trace
Main isotopes
1.592×105 y
Decay
α
Decay
229Th
SF
SF
Main isotopes
SF
Main isotopes
234U
234U
Main isotopes
234U
Main isotopes
0.005%
Main isotopes
2.455×105 y
Decay
α
Decay
230Th
SF
SF
Main isotopes
SF
Main isotopes
235U
235U
Main isotopes
235U
Main isotopes
0.720%
Main isotopes
7.04×108 y
Decay
α
Decay
231Th
SF
SF
Main isotopes
SF
Main isotopes
236U
236U
Main isotopes
236U
Main isotopes
trace
Main isotopes
2.342×107 y
Decay
α
Decay
232Th
SF
SF
Main isotopes
SF
Main isotopes
238U
238U
Main isotopes
238U
Main isotopes
99.3%
Main isotopes
4.463×109 y
Decay
α
Decay
234Th
SF
SF
Main isotopes
SF
Main isotopes
β−β−
β−β−
Main isotopes
β−β−
Main isotopes
238Pu
Main isotopes
Decay
mw- Isotope
abun­dance
half-life (t1/2)
mode
pro­duct
232U
synth
68.9 y
α
228Th
SF
233U
trace
1.592×105 y
α
229Th
SF
234U
0.005%
2.455×105 y
α
230Th
SF
235U
0.720%
7.04×108 y
α
231Th
SF
236U
trace
2.342×107 y
α
232Th
SF
238U
99.3%
4.463×109 y
α
234Th
SF
β−β−
238Pu
Pourbaix diagrams[110] · Compounds › Oxidation states and oxides › Carbonates
Uranium in a non-complexing aqueous medium(e.g. perchloric acid/sodium hydroxide).
Uranium in a non-complexing aqueous medium(e.g. perchloric acid/sodium hydroxide).
Col 1
Uranium in a non-complexing aqueous medium(e.g. perchloric acid/sodium hydroxide).
Col 2
Uranium in carbonate solution
Relative concentrations of the different chemical forms of uranium in a non-complexing aqueous medium(e.g. perchloric acid/sodium hydroxide).
Relative concentrations of the different chemical forms of uranium in a non-complexing aqueous medium(e.g. perchloric acid/sodium hydroxide).
Col 1
Relative concentrations of the different chemical forms of uranium in a non-complexing aqueous medium(e.g. perchloric acid/sodium hydroxide).
Col 2
Relative concentrations of the different chemical forms of uranium in an aqueous carbonate solution.
Uranium in a non-complexing aqueous medium(e.g. perchloric acid/sodium hydroxide).
Uranium in carbonate solution
Relative concentrations of the different chemical forms of uranium in a non-complexing aqueous medium(e.g. perchloric acid/sodium hydroxide).
Relative concentrations of the different chemical forms of uranium in an aqueous carbonate solution.

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