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Samarium

Updated: Wikipedia source

Samarium

Samarium is a chemical element; it has symbol Sm and atomic number 62. It is a moderately hard silvery metal that slowly oxidizes in air. Being a typical member of the lanthanide series, samarium usually has the oxidation state +3. Compounds of samarium(II) are also known, most notably the monoxide SmO, monochalcogenides SmS, SmSe and SmTe, as well as samarium(II) iodide. Discovered in 1879 by French chemist Paul-Émile Lecoq de Boisbaudran, samarium was named after the mineral samarskite from which it was isolated. The mineral itself was named after a Russian mine official, Colonel Vassili Samarsky-Bykhovets, who thus became the first person to have a chemical element named after him, though the name was indirect. Samarium occurs in concentration up to 2.8% in several minerals including cerite, gadolinite, samarskite, monazite and bastnäsite, the last two being the most common commercial sources of the element. These minerals are mostly found in China, the United States, Brazil, India, Sri Lanka and Australia; China is by far the world leader in samarium mining and production. The main commercial use of samarium is in samarium–cobalt magnets, which have permanent magnetization second only to neodymium magnets; however, samarium compounds can withstand significantly higher temperatures, above 700 °C (1,292 °F), without losing their permanent magnetic properties. The radioisotope samarium-153 is the active component of the drug samarium (153Sm) lexidronam (Quadramet), which kills cancer cells in lung cancer, prostate cancer, breast cancer and osteosarcoma. Another isotope, samarium-149, is a strong neutron absorber and so is added to control rods of nuclear reactors. It also forms as a decay product during reactor operation and is one of the important factors considered in reactor design and operation. Other uses of samarium include catalysis of chemical reactions, radioactive dating and X-ray lasers. Samarium(II) iodide, in particular, is a common reducing agent in chemical synthesis. Samarium has no biological role; some samarium salts are slightly toxic.

Infobox

Pronunciation
/səˈmɛəriəm/ ⓘ (sə-MAIR-ee-əm)
Appearance
silvery white
Atomic number (Z)
62
Group
f-block groups (no number)
Period
period 6
Block
f-block
Electron configuration
[Xe] 4f6 6s2
Electrons per shell
2, 8, 18, 24, 8, 2
Phase at STP
solid
Melting point
1345 K (1072 °C, 1962 °F)
Boiling point
2173 K (1900 °C, 3452 °F)
Density (at 20° C)
7.518 g/cm3
when liquid (at m.p.)
7.16 g/cm3
Heat of fusion
8.62 kJ/mol
Heat of vaporization
192 kJ/mol
Molar heat capacity
29.54 J/(mol·K)
P (Pa)
Vapor pressure P (Pa) 1 10 100 1 k 10 k 100 k at T (K) 1001 1106 1240 (1421) (1675) (2061)
at T (K)
1001
Oxidation states
common: 3 0, 1, 2
Electronegativity
Pauling scale: 1.17
Ionization energies
1st: 544.5 kJ/mol 2nd: 1070 kJ/mol 3rd: 2260 kJ/mol
Atomic radius
empirical: 180 pm
Covalent radius
198±8 pm
Natural occurrence
primordial
Crystal structure
rhombohedral (hR3)
Lattice constants
ar = 0.89834 nmα = 23.307°ah = 0.36291 nmch = 2.6207 nm (at 20 °C)
Thermal expansion
poly: 12.7 (at r.t.) µm/(m⋅K)
Thermal conductivity
13.3 W/(m⋅K)
Electrical resistivity
α, poly: 0.940 (at r.t.) µΩ⋅m
Magnetic ordering
paramagnetic
Molar magnetic susceptibility
1860.0×10−6 cm3/mol (291 K)
Young's modulus
49.7 GPa
Shear modulus
19.5 GPa
Bulk modulus
37.8 GPa
Speed of sound thin rod
2130 m/s (at 20 °C)
Poisson ratio
0.274
Vickers hardness
410–440 MPa
Brinell hardness
440–600 MPa
CAS Number
7440-19-9
Naming
after the mineral samarskite (itself named after Vassili Samarsky-Bykhovets)
Discovery
Lecoq de Boisbaudran (1879)
First isolation
Wilhelm Muthmann (1903)
Main isotopes
mw- body Main isotopes Decay Isotope abun­dance half-life (t1/2) mode pro­duct 144Sm 3.08% stable 145Sm synth 340 d ε 145Pm 146Sm trace 9.20×107 y α 142Nd 147Sm 15% 1.066×1011 y α 143Nd 148Sm 11.3% 6.3×1015 y α 144Nd 149Sm 13.8% stable 150Sm 7.37% stable 151Sm synth 94.6 y β− 151Eu 152Sm 26.7% stable 153Sm synth 46.285 h β− 153Eu 154Sm 22.7% stable
144Sm
3.08%
145Sm
synth
146Sm
trace
147Sm
15%
148Sm
11.3%
149Sm
13.8%
150Sm
7.37%
151Sm
synth
152Sm
26.7%
153Sm
synth
154Sm
22.7%

Tables

at T (K)
at T (K)
P (Pa)
at T (K)
1
1001
10
1106
100
1240
1 k
(1421)
10 k
(1675)
100 k
(2061)
P (Pa)
1
10
100
1 k
10 k
100 k
at T (K)
1001
1106
1240
(1421)
(1675)
(2061)
mw- Isotope
mw- Isotope
Main isotopes
mw- Isotope
Main isotopes
abun­dance
Main isotopes
half-life (t1/2)
Decay
mode
Decay
pro­duct
144Sm
144Sm
Main isotopes
144Sm
Main isotopes
3.08%
Main isotopes
stable
145Sm
145Sm
Main isotopes
145Sm
Main isotopes
synth
Main isotopes
340 d
Decay
ε
Decay
145Pm
146Sm
146Sm
Main isotopes
146Sm
Main isotopes
trace
Main isotopes
9.20×107 y
Decay
α
Decay
142Nd
147Sm
147Sm
Main isotopes
147Sm
Main isotopes
15%
Main isotopes
1.066×1011 y
Decay
α
Decay
143Nd
148Sm
148Sm
Main isotopes
148Sm
Main isotopes
11.3%
Main isotopes
6.3×1015 y
Decay
α
Decay
144Nd
149Sm
149Sm
Main isotopes
149Sm
Main isotopes
13.8%
Main isotopes
stable
150Sm
150Sm
Main isotopes
150Sm
Main isotopes
7.37%
Main isotopes
stable
151Sm
151Sm
Main isotopes
151Sm
Main isotopes
synth
Main isotopes
94.6 y
Decay
β−
Decay
151Eu
152Sm
152Sm
Main isotopes
152Sm
Main isotopes
26.7%
Main isotopes
stable
153Sm
153Sm
Main isotopes
153Sm
Main isotopes
synth
Main isotopes
46.285 h
Decay
β−
Decay
153Eu
154Sm
154Sm
Main isotopes
154Sm
Main isotopes
22.7%
Main isotopes
stable
Main isotopes
Decay
mw- Isotope
abun­dance
half-life (t1/2)
mode
pro­duct
144Sm
3.08%
stable
145Sm
synth
340 d
ε
145Pm
146Sm
trace
9.20×107 y
α
142Nd
147Sm
15%
1.066×1011 y
α
143Nd
148Sm
11.3%
6.3×1015 y
α
144Nd
149Sm
13.8%
stable
150Sm
7.37%
stable
151Sm
synth
94.6 y
β−
151Eu
152Sm
26.7%
stable
153Sm
synth
46.285 h
β−
153Eu
154Sm
22.7%
stable
· Compounds
Sm
Sm
Formula
Sm
Color
silvery
Symmetry
trigonal
Space group
R3m
No.
166
Pearson symbol
hR9
a (pm)
362.9
b (pm)
362.9
c (pm)
2621.3
Z
9
Density, g/cm3
7.52
Sm
Sm
Formula
Sm
Color
silvery
Symmetry
hexagonal
Space group
P63/mmc
No.
194
Pearson symbol
hP4
a (pm)
362
b (pm)
362
c (pm)
1168
Z
4
Density, g/cm3
7.54
Sm
Sm
Formula
Sm
Color
silvery
Symmetry
tetragonal
Space group
I4/mmm
No.
139
Pearson symbol
tI2
a (pm)
240.2
b (pm)
240.2
c (pm)
423.1
Z
2
Density, g/cm3
20.46
SmO
SmO
Formula
SmO
Color
golden
Symmetry
cubic
Space group
Fm3m
No.
225
Pearson symbol
cF8
a (pm)
494.3
b (pm)
494.3
c (pm)
494.3
Z
4
Density, g/cm3
9.15
Sm2O3
Sm2O3
Formula
Sm2O3
Symmetry
trigonal
Space group
P3m1
No.
164
Pearson symbol
hP5
a (pm)
377.8
b (pm)
377.8
c (pm)
594
Z
1
Density, g/cm3
7.89
Sm2O3
Sm2O3
Formula
Sm2O3
Symmetry
monoclinic
Space group
C2/m
No.
12
Pearson symbol
mS30
a (pm)
1418
b (pm)
362.4
c (pm)
885.5
Z
6
Density, g/cm3
7.76
Sm2O3
Sm2O3
Formula
Sm2O3
Symmetry
cubic
Space group
Ia3
No.
206
Pearson symbol
cI80
a (pm)
1093
b (pm)
1093
c (pm)
1093
Z
16
Density, g/cm3
7.1
SmH2
SmH2
Formula
SmH2
Symmetry
cubic
Space group
Fm3m
No.
225
Pearson symbol
cF12
a (pm)
537.73
b (pm)
537.73
c (pm)
537.73
Z
4
Density, g/cm3
6.51
SmH3
SmH3
Formula
SmH3
Symmetry
hexagonal
Space group
P3c1
No.
165
Pearson symbol
hP24
a (pm)
377.1
b (pm)
377.1
c (pm)
667.2
Z
6
Sm2B5
Sm2B5
Formula
Sm2B5
Color
gray
Symmetry
monoclinic
Space group
P21/c
No.
14
Pearson symbol
mP28
a (pm)
717.9
b (pm)
718
c (pm)
720.5
Z
4
Density, g/cm3
6.49
SmB2
SmB2
Formula
SmB2
Symmetry
hexagonal
Space group
P6/mmm
No.
191
Pearson symbol
hP3
a (pm)
331
b (pm)
331
c (pm)
401.9
Z
1
Density, g/cm3
7.49
SmB4
SmB4
Formula
SmB4
Symmetry
tetragonal
Space group
P4/mbm
No.
127
Pearson symbol
tP20
a (pm)
717.9
b (pm)
717.9
c (pm)
406.7
Z
4
Density, g/cm3
6.14
SmB6
SmB6
Formula
SmB6
Symmetry
cubic
Space group
Pm3m
No.
221
Pearson symbol
cP7
a (pm)
413.4
b (pm)
413.4
c (pm)
413.4
Z
1
Density, g/cm3
5.06
SmB66
SmB66
Formula
SmB66
Symmetry
cubic
Space group
Fm3c
No.
226
Pearson symbol
cF1936
a (pm)
2348.7
b (pm)
2348.7
c (pm)
2348.7
Z
24
Density, g/cm3
2.66
Sm2C3
Sm2C3
Formula
Sm2C3
Symmetry
cubic
Space group
I43d
No.
220
Pearson symbol
cI40
a (pm)
839.89
b (pm)
839.89
c (pm)
839.89
Z
8
Density, g/cm3
7.55
SmC2
SmC2
Formula
SmC2
Symmetry
tetragonal
Space group
I4/mmm
No.
139
Pearson symbol
tI6
a (pm)
377
b (pm)
377
c (pm)
633.1
Z
2
Density, g/cm3
6.44
SmF2
SmF2
Formula
SmF2
Color
purple
Symmetry
cubic
Space group
Fm3m
No.
225
Pearson symbol
cF12
a (pm)
587.1
b (pm)
587.1
c (pm)
587.1
Z
4
Density, g/cm3
6.18
SmF3
SmF3
Formula
SmF3
Color
white
Symmetry
orthorhombic
Space group
Pnma
No.
62
Pearson symbol
oP16
a (pm)
667.22
b (pm)
705.85
c (pm)
440.43
Z
4
Density, g/cm3
6.64
SmCl2
SmCl2
Formula
SmCl2
Color
brown
Symmetry
orthorhombic
Space group
Pnma
No.
62
Pearson symbol
oP12
a (pm)
756.28
b (pm)
450.77
c (pm)
901.09
Z
4
Density, g/cm3
4.79
SmCl3
SmCl3
Formula
SmCl3
Color
yellow
Symmetry
hexagonal
Space group
P63/m
No.
176
Pearson symbol
hP8
a (pm)
737.33
b (pm)
737.33
c (pm)
416.84
Z
2
Density, g/cm3
4.35
SmBr2
SmBr2
Formula
SmBr2
Color
brown
Symmetry
orthorhombic
Space group
Pnma
No.
62
Pearson symbol
oP12
a (pm)
797.7
b (pm)
475.4
c (pm)
950.6
Z
4
Density, g/cm3
5.72
SmBr3
SmBr3
Formula
SmBr3
Color
yellow
Symmetry
orthorhombic
Space group
Cmcm
No.
63
Pearson symbol
oS16
a (pm)
404
b (pm)
1265
c (pm)
908
Z
2
Density, g/cm3
5.58
SmI2
SmI2
Formula
SmI2
Color
green
Symmetry
monoclinic
Space group
P21/c
No.
14
Pearson symbol
mP12
SmI3
SmI3
Formula
SmI3
Color
orange
Symmetry
trigonal
Space group
R3
No.
63
Pearson symbol
hR24
a (pm)
749
b (pm)
749
c (pm)
2080
Z
6
Density, g/cm3
5.24
SmN
SmN
Formula
SmN
Symmetry
cubic
Space group
Fm3m
No.
225
Pearson symbol
cF8
a (pm)
357
b (pm)
357
c (pm)
357
Z
4
Density, g/cm3
8.48
SmP
SmP
Formula
SmP
Symmetry
cubic
Space group
Fm3m
No.
225
Pearson symbol
cF8
a (pm)
576
b (pm)
576
c (pm)
576
Z
4
Density, g/cm3
6.3
SmAs
SmAs
Formula
SmAs
Symmetry
cubic
Space group
Fm3m
No.
225
Pearson symbol
cF8
a (pm)
591.5
b (pm)
591.5
c (pm)
591.5
Z
4
Density, g/cm3
7.23
Formula
Color
Symmetry
Space group
No.
Pearson symbol
a (pm)
b (pm)
c (pm)
Z
Density, g/cm3
Sm
silvery
trigonal
R3m
166
hR9
362.9
362.9
2621.3
9
7.52
Sm
silvery
hexagonal
P63/mmc
194
hP4
362
362
1168
4
7.54
Sm
silvery
tetragonal
I4/mmm
139
tI2
240.2
240.2
423.1
2
20.46
SmO
golden
cubic
Fm3m
225
cF8
494.3
494.3
494.3
4
9.15
Sm2O3
trigonal
P3m1
164
hP5
377.8
377.8
594
1
7.89
Sm2O3
monoclinic
C2/m
12
mS30
1418
362.4
885.5
6
7.76
Sm2O3
cubic
Ia3
206
cI80
1093
1093
1093
16
7.1
SmH2
cubic
Fm3m
225
cF12
537.73
537.73
537.73
4
6.51
SmH3
hexagonal
P3c1
165
hP24
377.1
377.1
667.2
6
Sm2B5
gray
monoclinic
P21/c
14
mP28
717.9
718
720.5
4
6.49
SmB2
hexagonal
P6/mmm
191
hP3
331
331
401.9
1
7.49
SmB4
tetragonal
P4/mbm
127
tP20
717.9
717.9
406.7
4
6.14
SmB6
cubic
Pm3m
221
cP7
413.4
413.4
413.4
1
5.06
SmB66
cubic
Fm3c
226
cF1936
2348.7
2348.7
2348.7
24
2.66
Sm2C3
cubic
I43d
220
cI40
839.89
839.89
839.89
8
7.55
SmC2
tetragonal
I4/mmm
139
tI6
377
377
633.1
2
6.44
SmF2
purple
cubic
Fm3m
225
cF12
587.1
587.1
587.1
4
6.18
SmF3
white
orthorhombic
Pnma
62
oP16
667.22
705.85
440.43
4
6.64
SmCl2
brown
orthorhombic
Pnma
62
oP12
756.28
450.77
901.09
4
4.79
SmCl3
yellow
hexagonal
P63/m
176
hP8
737.33
737.33
416.84
2
4.35
SmBr2
brown
orthorhombic
Pnma
62
oP12
797.7
475.4
950.6
4
5.72
SmBr3
yellow
orthorhombic
Cmcm
63
oS16
404
1265
908
2
5.58
SmI2
green
monoclinic
P21/c
14
mP12
SmI3
orange
trigonal
R3
63
hR24
749
749
2080
6
5.24
SmN
cubic
Fm3m
225
cF8
357
357
357
4
8.48
SmP
cubic
Fm3m
225
cF8
576
576
576
4
6.3
SmAs
cubic
Fm3m
225
cF8
591.5
591.5
591.5
4
7.23

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