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Periodic table

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Periodic table

The periodic table, also known as the periodic table of the elements, is an ordered arrangement of the chemical elements into rows ("periods") and columns ("groups"). An icon of chemistry, the periodic table is widely used in physics and other sciences. It is a depiction of the periodic law, which states that when the elements are arranged in order of their atomic numbers an approximate recurrence of their properties is evident. The table is divided into four roughly rectangular areas called blocks. Elements in the same group tend to show similar chemical characteristics. Vertical, horizontal and diagonal trends characterize the periodic table. Metallic character increases going down a group and from right to left across a period. Nonmetallic character increases going from the bottom left of the periodic table to the top right. The first periodic table to become generally accepted was that of the Russian chemist Dmitri Mendeleev in 1869; he formulated the periodic law as a dependence of chemical properties on atomic mass. As not all elements were then known, there were gaps in his periodic table, and Mendeleev successfully used the periodic law to predict some properties of some of the missing elements. The periodic law was recognized as a fundamental discovery in the late 19th century. It was explained early in the 20th century, with the discovery of atomic numbers and associated pioneering work in quantum mechanics, both ideas serving to illuminate the internal structure of the atom. A recognisably modern form of the table was reached in 1945 with Glenn T. Seaborg's discovery that the actinides were in fact f-block rather than d-block elements. The periodic table and law have become a central and indispensable part of modern chemistry. The periodic table continues to evolve with the progress of science. In nature, only elements up to atomic number 94 exist; elements beyond that can only be synthesized in the laboratory. By 2010, the first 118 elements were known, thereby completing the first seven rows of the table; however, chemical characterization is still needed for the heaviest elements to confirm that their properties match their positions. New discoveries will extend the table beyond these seven rows, though it is not yet known how many more elements are possible; moreover, theoretical calculations suggest that this unknown region will not follow the patterns of the known part of the table. Some scientific discussion also continues regarding whether some elements are correctly positioned in the table. Many alternative representations of the periodic law exist, and there is some discussion as to whether there is an optimal form of the periodic table.

Tables

· Structure › Electron configurations
Orbital
Orbital
ℓ =
Orbital
0
s
1
p
2
d
3
f
4
g
5
h
6
i
n = 1
n = 1
ℓ =
n = 1
0
1s
2
2
n = 2
n = 2
ℓ =
n = 2
0
2s
1
2p
3
8
n = 3
n = 3
ℓ =
n = 3
0
3s
1
3p
2
3d
4
18
n = 4
n = 4
ℓ =
n = 4
0
4s
1
4p
2
4d
3
4f
5
32
n = 5
n = 5
ℓ =
n = 5
0
5s
1
5p
2
5d
3
5f
4
5g
6
50
n = 6
n = 6
ℓ =
n = 6
0
6s
1
6p
2
6d
3
6f
4
6g
5
6h
Shell capacity (2n2)
72
n = 7
n = 7
ℓ =
n = 7
0
7s
1
7p
2
7d
3
7f
4
7g
5
7h
6
7i
Shell capacity (2n2)
98
Subshell capacity (4ℓ+2)
Subshell capacity (4ℓ+2)
ℓ =
Subshell capacity (4ℓ+2)
0
2
1
6
2
10
3
14
4
18
5
22
6
26
ℓ =
0
1
2
3
4
5
6
Shell capacity (2n2)
Orbital
s
p
d
f
g
h
i
n = 1
1s
2
n = 2
2s
2p
8
n = 3
3s
3p
3d
18
n = 4
4s
4p
4d
4f
32
n = 5
5s
5p
5d
5f
5g
50
n = 6
6s
6p
6d
6f
6g
6h
72
n = 7
7s
7p
7d
7f
7g
7h
7i
98
Subshell capacity (4ℓ+2)
2
6
10
14
18
22
26
· Structure › Electron configurations › Order of subshell filling
3 Li
3 Li
1 H
3 Li
Col 2
4 Be
Col 3
5 B
Col 4
6 C
Col 5
7 N
Col 6
8 O
Col 7
9 F
2 He
10 Ne
2×1 = 2 elements 1s 0p
2×(1+3) = 8 elements 2s 2p
11 Na
11 Na
1 H
11 Na
Col 2
12 Mg
Col 3
13 Al
Col 4
14 Si
Col 5
15 P
Col 6
16 S
Col 7
17 Cl
2 He
18 Ar
2×1 = 2 elements 1s 0p
2×(1+3) = 8 elements 3s 3p
1 H
2 He
2×1 = 2 elements 1s 0p
3 Li
4 Be
5 B
6 C
7 N
8 O
9 F
10 Ne
2×(1+3) = 8 elements 2s 2p
11 Na
12 Mg
13 Al
14 Si
15 P
16 S
17 Cl
18 Ar
2×(1+3) = 8 elements 3s 3p
· Structure › Electron configurations › Order of subshell filling
3 Li
3 Li
1 H
3 Li
Col 2
4 Be
11 Na
11 Na
1 H
11 Na
Col 2
12 Mg
19 K
19 K
1 H
19 K
Col 2
20 Ca
Col 3
21 Sc
Col 4
22 Ti
Col 5
23 V
Col 6
24 Cr
Col 7
25 Mn
Col 8
26 Fe
Col 9
27 Co
Col 10
28 Ni
Col 11
29 Cu
Col 12
30 Zn
37 Rb
37 Rb
1 H
37 Rb
Col 2
38 Sr
Col 3
39 Y
Col 4
40 Zr
Col 5
41 Nb
Col 6
42 Mo
Col 7
43 Tc
Col 8
44 Ru
Col 9
45 Rh
Col 10
46 Pd
Col 11
47 Ag
Col 12
48 Cd
1 H
3 Li
4 Be
11 Na
12 Mg
19 K
20 Ca
21 Sc
22 Ti
23 V
24 Cr
25 Mn
26 Fe
27 Co
28 Ni
29 Cu
30 Zn
37 Rb
38 Sr
39 Y
40 Zr
41 Nb
42 Mo
43 Tc
44 Ru
45 Rh
46 Pd
47 Ag
48 Cd
3 Li
3 Li
1 H
3 Li
Col 2
4 Be
11 Na
11 Na
1 H
11 Na
Col 2
12 Mg
19 K
19 K
1 H
19 K
Col 2
20 Ca
37 Rb
37 Rb
1 H
37 Rb
Col 2
38 Sr
55 Cs
55 Cs
1 H
55 Cs
Col 2
56 Ba
Col 3
57 La
Col 4
58 Ce
Col 5
59 Pr
Col 6
60 Nd
Col 7
61 Pm
Col 8
62 Sm
Col 9
63 Eu
Col 10
64 Gd
Col 11
65 Tb
Col 12
66 Dy
87 Fr
87 Fr
1 H
87 Fr
Col 2
88 Ra
Col 3
89 Ac
Col 4
90 Th
Col 5
91 Pa
Col 6
92 U
Col 7
93 Np
Col 8
94 Pu
Col 9
95 Am
Col 10
96 Cm
Col 11
97 Bk
Col 12
98 Cf
1 H
3 Li
4 Be
11 Na
12 Mg
19 K
20 Ca
37 Rb
38 Sr
55 Cs
56 Ba
57 La
58 Ce
59 Pr
60 Nd
61 Pm
62 Sm
63 Eu
64 Gd
65 Tb
66 Dy
87 Fr
88 Ra
89 Ac
90 Th
91 Pa
92 U
93 Np
94 Pu
95 Am
96 Cm
97 Bk
98 Cf

References

  1. The question of how many natural elements there are is quite complicated and is not fully resolved. The heaviest element that occurs in large quantities on Earth is element 92, uranium. However, uranium can undergo spont
  2. Some isotopes currently considered stable are theoretically expected to be radioactive with extremely long half-lives: for instance, all the stable isotopes of elements 62 (samarium), 63 (europium), and all elements from
  3. The half-life of plutonium's most stable isotope is just long enough that it should also be a primordial element. A 1971 study claimed to have detected primordial plutonium, but a more recent study from 2012 could not de
  4. Tiny traces of plutonium are also continually brought to Earth via cosmic rays.
  5. See for example the periodic table poster sold by Sigma-Aldrich.
    https://www.sigmaaldrich.com/SG/en/product/aldrich/z543209
  6. Strictly speaking, one cannot draw an orbital such that the electron is guaranteed to be inside it, but it can be drawn to guarantee a 90% probability of this for example.
  7. Authors differ on whether the n + ℓ rule has yet been derived from quantum mechanics. Scerri claims that it has not, despite several attempts to do so. On the other hand, Ostrovsky, who has claimed such justification fro
  8. Once two to four electrons are removed, the d and f orbitals usually become lower in energy than the s ones: 1s ≪ 2s < 2p ≪ 3s < 3p ≪ 3d < 4s < 4p ≪ 4d < 5s < 5p ≪ 4f < 5d < 6s < 6p ≪ 5f < 6d < 7s < 7p ≪ ... and in the
  9. In fact, electron configurations represent a first-order approximation: an atom really exists in a superposition of multiple configurations, and electrons in an atom are indistinguishable. The elements in the d- and f-bl
  10. Compounds that would use the 6d orbitals of nihonium as valence orbitals have been theoretically investigated, but they are all expected to be too unstable to observe.
  11. Properties of the p-block elements nevertheless do affect the succeeding s-block elements. The 3s shell in sodium is above a kainosymmetric 2p core, but the 4s shell in potassium is above the much larger 3p core. Hence w
  12. There are many lower oxides as well: for example, phosphorus in group 15 forms two oxides, P2O3 and P2O5.
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