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Oxygen

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Oxygen

Oxygen is a chemical element; it has the symbol O and its atomic number is 8. It is a member of the chalcogen group in the periodic table, a highly reactive nonmetal, and a potent oxidizing agent that readily forms oxides with most elements as well as with other compounds. Oxygen is the most abundant element in Earth's crust, making up almost half of the Earth's crust in the form of various oxides such as water, carbon dioxide, iron oxides and silicates. It is also the third-most abundant element in the universe after hydrogen and helium. At standard temperature and pressure, two oxygen atoms will bind covalently to form dioxygen, a colorless and odorless diatomic gas with the chemical formula O2. Dioxygen gas currently constitutes approximately 20.95% molar fraction of the Earth's atmosphere, though this has changed considerably over long periods of time in Earth's history. A much rarer triatomic allotrope of oxygen, ozone (O3), strongly absorbs the UVB and UVC wavelengths and forms a protective ozone layer at the lower stratosphere, which shields the biosphere from ionizing ultraviolet radiation. However, ozone present at the surface is a corrosive byproduct of smog and thus an air pollutant. All eukaryotic organisms, including plants, animals, fungi, algae and most protists, need oxygen for cellular respiration, a process that extracts chemical energy by the reaction of oxygen with organic molecules derived from food and releases carbon dioxide as a waste product. Many major classes of organic molecules in living organisms contain oxygen atoms, such as proteins, nucleic acids, carbohydrates and fats, as do the major constituent inorganic compounds of animal shells, teeth, and bone. Most of the mass of living organisms is oxygen as a component of water, the major constituent of lifeforms. Oxygen in Earth's atmosphere is produced by biotic photosynthesis, in which photon energy in sunlight is captured by chlorophyll to split water molecules and then react with carbon dioxide to produce carbohydrates and oxygen is released as a byproduct. Oxygen is too chemically reactive to remain a free element in air without being continuously replenished by the photosynthetic activities of autotroph such as cyanobacteria, chloroplast-bearing algae and plants. Oxygen was isolated by Michael Sendivogius before 1604, but it is commonly believed that the element was discovered independently by Carl Wilhelm Scheele, in Uppsala, in 1773 or earlier, and Joseph Priestley in Wiltshire, in 1774. Priority is often given for Priestley because his work was published first. Priestley, however, called oxygen "dephlogisticated air", and did not recognize it as a chemical element. In 1777, Antoine Lavoisier first recognized oxygen as a chemical element and correctly characterized the role it plays in combustion. Common industrial uses of oxygen include production of steel, plastics and textiles, brazing, welding and cutting of steels and other metals, rocket propellant, oxygen therapy, and life-support systems in aircraft, submarines, spaceflight and diving.

Infobox

Allotropes
O2, O3 (ozone) and more (see Allotropes of oxygen)
Appearance
gas: colorlessliquid and solid: pale blue
Atomic number (Z)
8
Group
group 16 (chalcogens)
Period
period 2
Block
p-block
Electron configuration
[He] 2s2 2p4
Electrons per shell
2, 6
Phase at STP
gas
Melting point
(O2) 54.36 K (−218.79 °C, −361.82 °F)
Boiling point
(O2) 90.188 K (−182.962 °C, −297.332 °F)
Density (at STP)
1.429 g/L
when liquid (at b.p.)
1.141 g/cm3
Triple point
54.361 K, 0.1463 kPa
Critical point
154.581 K, 5.043 MPa
Heat of fusion
(O2) 0.444 kJ/mol
Heat of vaporization
(O2) 6.82 kJ/mol
Molar heat capacity
(O2) 29.378 J/(mol·K)
P (Pa)
Vapor pressure P (Pa) 1 10 100 1 k 10 k 100 k at T (K) 61 73 90
Oxidation states
common: −2 −1, 0, 1, 2
Electronegativity
Pauling scale: 3.44
Ionization energies
1st: 1313.9 kJ/mol 2nd: 3388.3 kJ/mol 3rd: 5300.5 kJ/mol (more)
Covalent radius
66±2 pm
Van der Waals radius
152 pm
Natural occurrence
primordial
Crystal structure
cubic (cP16)
Lattice constant
a = 678.28 pm (at t.p.)
Thermal conductivity
26.58×10−3 W/(m⋅K)
Magnetic ordering
paramagnetic
Molar magnetic susceptibility
3449.0×10−6 cm3/mol (293 K)
Speed of sound
330 m/s (gas, at 27 °C)
CAS Number
7782-44-7
Naming
from the Greek ὀξύς (acid, literally 'sharp', from the taste of acids) and -γενής (producer)
Discovery
Michael SendivogiusCarl Wilhelm Scheele (1604, 1771)
Named by
Antoine Lavoisier (1777)
Main isotopes
mw- body Main isotopes Decay Isotope abun­dance half-life (t1/2) mode pro­duct 15O trace 122.27 s β 15N 16O 99.8% stable 17O 0.0384% stable 18O 0.205% stable
15O
trace
16O
99.8%
17O
0.0384%
18O
0.205%

Tables

at T (K)
at T (K)
P (Pa)
at T (K)
1 k
61
10 k
73
100 k
90
P (Pa)
1
10
100
1 k
10 k
100 k
at T (K)
61
73
90
mw- Isotope
mw- Isotope
Main isotopes
mw- Isotope
Main isotopes
abun­dance
Main isotopes
half-life (t1/2)
Decay
mode
Decay
pro­duct
15O
15O
Main isotopes
15O
Main isotopes
trace
Main isotopes
122.27 s
Decay
β+
Decay
15N
16O
16O
Main isotopes
16O
Main isotopes
99.8%
Main isotopes
stable
17O
17O
Main isotopes
17O
Main isotopes
0.0384%
Main isotopes
stable
18O
18O
Main isotopes
18O
Main isotopes
0.205%
Main isotopes
stable
Main isotopes
Decay
mw- Isotope
abun­dance
half-life (t1/2)
mode
pro­duct
15O
trace
122.27 s
β+
15N
16O
99.8%
stable
17O
0.0384%
stable
18O
0.205%
stable
Oxygen gas dissolved in water at sea-level(milliliters per liter) · Characteristics › Physical properties
Freshwater
Freshwater
Col 1
Freshwater
5 °C (41 °F)
9.00
25 °C (77 °F)
6.04
Seawater
Seawater
Col 1
Seawater
5 °C (41 °F)
7.20
25 °C (77 °F)
4.95
5 °C (41 °F)
25 °C (77 °F)
Freshwater
9.00
6.04
Seawater
7.20
4.95
· Characteristics › Physical properties
100
100
Temperature (K)
100
Density (kg/m3)
3.945
Specific heat (kJ/(kg·K))
0.962
Dynamic viscosity (kg/(m·s))
7.64E-06
Kinematic viscosity (m2/s)
1.94E-06
Thermal conductivity (W/(m·K))
0.00925
Thermal diffusivity (m2/s)
2.44E-06
Prandtl Number
0.796
150
150
Temperature (K)
150
Density (kg/m3)
2.585
Specific heat (kJ/(kg·K))
0.921
Dynamic viscosity (kg/(m·s))
1.15E-05
Kinematic viscosity (m2/s)
4.44E-06
Thermal conductivity (W/(m·K))
0.0138
Thermal diffusivity (m2/s)
5.80E-06
Prandtl Number
0.766
200
200
Temperature (K)
200
Density (kg/m3)
1.93
Specific heat (kJ/(kg·K))
0.915
Dynamic viscosity (kg/(m·s))
1.48E-05
Kinematic viscosity (m2/s)
7.64E-06
Thermal conductivity (W/(m·K))
0.0183
Thermal diffusivity (m2/s)
1.04E-05
Prandtl Number
0.737
250
250
Temperature (K)
250
Density (kg/m3)
1.542
Specific heat (kJ/(kg·K))
0.915
Dynamic viscosity (kg/(m·s))
1.79E-05
Kinematic viscosity (m2/s)
1.16E-05
Thermal conductivity (W/(m·K))
0.0226
Thermal diffusivity (m2/s)
1.60E-05
Prandtl Number
0.723
300
300
Temperature (K)
300
Density (kg/m3)
1.284
Specific heat (kJ/(kg·K))
0.92
Dynamic viscosity (kg/(m·s))
2.07E-05
Kinematic viscosity (m2/s)
1.61E-05
Thermal conductivity (W/(m·K))
0.0268
Thermal diffusivity (m2/s)
2.27E-05
Prandtl Number
0.711
350
350
Temperature (K)
350
Density (kg/m3)
1.1
Specific heat (kJ/(kg·K))
0.929
Dynamic viscosity (kg/(m·s))
2.34E-05
Kinematic viscosity (m2/s)
2.12E-05
Thermal conductivity (W/(m·K))
0.0296
Thermal diffusivity (m2/s)
2.90E-05
Prandtl Number
0.733
400
400
Temperature (K)
400
Density (kg/m3)
0.962
Specific heat (kJ/(kg·K))
1.0408
Dynamic viscosity (kg/(m·s))
2.58E-05
Kinematic viscosity (m2/s)
2.68E-05
Thermal conductivity (W/(m·K))
0.033
Thermal diffusivity (m2/s)
3.64E-05
Prandtl Number
0.737
450
450
Temperature (K)
450
Density (kg/m3)
0.8554
Specific heat (kJ/(kg·K))
0.956
Dynamic viscosity (kg/(m·s))
2.81E-05
Kinematic viscosity (m2/s)
3.29E-05
Thermal conductivity (W/(m·K))
0.0363
Thermal diffusivity (m2/s)
4.44E-05
Prandtl Number
0.741
500
500
Temperature (K)
500
Density (kg/m3)
0.7698
Specific heat (kJ/(kg·K))
0.972
Dynamic viscosity (kg/(m·s))
3.03E-05
Kinematic viscosity (m2/s)
3.94E-05
Thermal conductivity (W/(m·K))
0.0412
Thermal diffusivity (m2/s)
5.51E-05
Prandtl Number
0.716
550
550
Temperature (K)
550
Density (kg/m3)
0.6998
Specific heat (kJ/(kg·K))
0.988
Dynamic viscosity (kg/(m·s))
3.24E-05
Kinematic viscosity (m2/s)
4.63E-05
Thermal conductivity (W/(m·K))
0.0441
Thermal diffusivity (m2/s)
6.38E-05
Prandtl Number
0.726
600
600
Temperature (K)
600
Density (kg/m3)
0.6414
Specific heat (kJ/(kg·K))
1.003
Dynamic viscosity (kg/(m·s))
3.44E-05
Kinematic viscosity (m2/s)
5.36E-05
Thermal conductivity (W/(m·K))
0.0473
Thermal diffusivity (m2/s)
7.35E-05
Prandtl Number
0.729
700
700
Temperature (K)
700
Density (kg/m3)
0.5498
Specific heat (kJ/(kg·K))
1.031
Dynamic viscosity (kg/(m·s))
3.81E-05
Kinematic viscosity (m2/s)
6.93E-05
Thermal conductivity (W/(m·K))
0.0528
Thermal diffusivity (m2/s)
9.31E-05
Prandtl Number
0.744
800
800
Temperature (K)
800
Density (kg/m3)
0.481
Specific heat (kJ/(kg·K))
1.054
Dynamic viscosity (kg/(m·s))
4.15E-05
Kinematic viscosity (m2/s)
8.63E-05
Thermal conductivity (W/(m·K))
0.0589
Thermal diffusivity (m2/s)
1.16E-04
Prandtl Number
0.743
900
900
Temperature (K)
900
Density (kg/m3)
0.4275
Specific heat (kJ/(kg·K))
1.074
Dynamic viscosity (kg/(m·s))
4.47E-05
Kinematic viscosity (m2/s)
1.05E-04
Thermal conductivity (W/(m·K))
0.0649
Thermal diffusivity (m2/s)
1.41E-04
Prandtl Number
0.74
1000
1000
Temperature (K)
1000
Density (kg/m3)
0.3848
Specific heat (kJ/(kg·K))
1.09
Dynamic viscosity (kg/(m·s))
4.77E-05
Kinematic viscosity (m2/s)
1.24E-04
Thermal conductivity (W/(m·K))
0.071
Thermal diffusivity (m2/s)
1.69E-04
Prandtl Number
0.733
1100
1100
Temperature (K)
1100
Density (kg/m3)
0.3498
Specific heat (kJ/(kg·K))
1.103
Dynamic viscosity (kg/(m·s))
5.06E-05
Kinematic viscosity (m2/s)
1.45E-04
Thermal conductivity (W/(m·K))
0.0758
Thermal diffusivity (m2/s)
1.96E-04
Prandtl Number
0.736
1200
1200
Temperature (K)
1200
Density (kg/m3)
0.3206
Specific heat (kJ/(kg·K))
1.0408
Dynamic viscosity (kg/(m·s))
5.33E-05
Kinematic viscosity (m2/s)
1.661E-04
Thermal conductivity (W/(m·K))
0.0819
Thermal diffusivity (m2/s)
2.29E-04
Prandtl Number
0.725
1300
1300
Temperature (K)
1300
Density (kg/m3)
0.296
Specific heat (kJ/(kg·K))
1.125
Dynamic viscosity (kg/(m·s))
5.88E-05
Kinematic viscosity (m2/s)
1.99E-04
Thermal conductivity (W/(m·K))
0.0871
Thermal diffusivity (m2/s)
2.62E-04
Prandtl Number
0.721
Temperature (K)
Density (kg/m3)
Specific heat (kJ/(kg·K))
Dynamic viscosity (kg/(m·s))
Kinematic viscosity (m2/s)
Thermal conductivity (W/(m·K))
Thermal diffusivity (m2/s)
Prandtl Number
100
3.945
0.962
7.64E-06
1.94E-06
0.00925
2.44E-06
0.796
150
2.585
0.921
1.15E-05
4.44E-06
0.0138
5.80E-06
0.766
200
1.93
0.915
1.48E-05
7.64E-06
0.0183
1.04E-05
0.737
250
1.542
0.915
1.79E-05
1.16E-05
0.0226
1.60E-05
0.723
300
1.284
0.92
2.07E-05
1.61E-05
0.0268
2.27E-05
0.711
350
1.1
0.929
2.34E-05
2.12E-05
0.0296
2.90E-05
0.733
400
0.962
1.0408
2.58E-05
2.68E-05
0.033
3.64E-05
0.737
450
0.8554
0.956
2.81E-05
3.29E-05
0.0363
4.44E-05
0.741
500
0.7698
0.972
3.03E-05
3.94E-05
0.0412
5.51E-05
0.716
550
0.6998
0.988
3.24E-05
4.63E-05
0.0441
6.38E-05
0.726
600
0.6414
1.003
3.44E-05
5.36E-05
0.0473
7.35E-05
0.729
700
0.5498
1.031
3.81E-05
6.93E-05
0.0528
9.31E-05
0.744
800
0.481
1.054
4.15E-05
8.63E-05
0.0589
1.16E-04
0.743
900
0.4275
1.074
4.47E-05
1.05E-04
0.0649
1.41E-04
0.74
1000
0.3848
1.09
4.77E-05
1.24E-04
0.071
1.69E-04
0.733
1100
0.3498
1.103
5.06E-05
1.45E-04
0.0758
1.96E-04
0.736
1200
0.3206
1.0408
5.33E-05
1.661E-04
0.0819
2.29E-04
0.725
1300
0.296
1.125
5.88E-05
1.99E-04
0.0871
2.62E-04
0.721
Ten most common elements in the Milky Way Galaxy estimated spectroscopically[70] · Characteristics › Occurrence
1
1
Z
1
Element
Hydrogen
Mass fraction in parts per million
739,000
2
2
Z
2
Element
Helium
Mass fraction in parts per million
240,000
8
8
Z
8
Element
Oxygen
Mass fraction in parts per million
10,400
6
6
Z
6
Element
Carbon
Mass fraction in parts per million
4,600
10
10
Z
10
Element
Neon
Mass fraction in parts per million
1,340
26
26
Z
26
Element
Iron
Mass fraction in parts per million
1,090
7
7
Z
7
Element
Nitrogen
Mass fraction in parts per million
960
14
14
Z
14
Element
Silicon
Mass fraction in parts per million
650
12
12
Z
12
Element
Magnesium
Mass fraction in parts per million
580
16
16
Z
16
Element
Sulfur
Mass fraction in parts per million
440
Z
Element
Mass fraction in parts per million
1
Hydrogen
739,000
2
Helium
240,000
8
Oxygen
10,400
6
Carbon
4,600
10
Neon
1,340
26
Iron
1,090
7
Nitrogen
960
14
Silicon
650
12
Magnesium
580
16
Sulfur
440
Partial pressures of oxygen in the human body (PO2) · Biological production and role of O<sub>2</sub> › Living organisms
kPa
kPa
Unit
kPa
Alveolar pulmonary gas pressures
14.2
Arterial blood oxygen
11-13
Venous blood gas
4.0-5.3
mmHg
mmHg
Unit
mmHg
Alveolar pulmonary gas pressures
107
Arterial blood oxygen
75-100
Venous blood gas
30-40
Unit
Alveolar pulmonary gas pressures
Arterial blood oxygen
Venous blood gas
kPa
14.2
11-13
4.0-5.3
mmHg
107
75-100
30-40

References

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