| # | Portrait | Name (born – died) | Home state | Tenure in office | Appointer (President) |
| From | To | Time in office |
| 1 | | Braj Kumar Nehru ICS (Retd) (1909–2001) | Uttar Pradesh | 21 January 1972 | 20 September 1973 | 1 year, 242 days | V. V. Giri |
| 2 | | Lallan Prasad Singh ICS (Retd) (1912–1998) | Bihar | 21 September 1973 | 11 August 1981 | 7 years, 323 days |
| 3 | | S. M. H. Burney IAS (Retd) (1924–2014) | Uttar Pradesh | 11 August 1981 | 11 June 1984[§] | 2 years, 305 days | Neelam Sanjiva Reddy |
| 4 | | General K. V. Krishna Rao (Retd) PVSM (1923–2016) | Andhra Pradesh | 11 June 1984 | 10 July 1989[§] | 5 years, 29 days | Zail Singh |
| 5 | | Chintamani Panigrahi (1922–2000) | Orissa | 10 July 1989 | 19 March 1993[‡] | 3 years, 252 days | Ramaswamy Venkataraman |
| 6 | | K. V. Raghunatha Reddy (1924–2002) (Additional Charge) | Andhra Pradesh | 20 March 1993 | 30 August 1993[§] | 163 days | Shankar Dayal Sharma |
| 7 | | Lieutenant General V. K. Nayar (Retd) PVSM SM (d. 2015) | – | 30 August 1993 | 22 December 1994[‡] | 1 year, 114 days |
| 8 | | Oudh Narayan Shrivastava IPS (Retd) (born 1935) (Additional charge till 11 November 1996) | Madhya Pradesh | 23 December 1994 | 1 December 1999 | 4 years, 343 days |
| 9 | | Ved Marwah IPS (Retd) (1934–2020) | National Capital Territory of Delhi | 2 December 1999 | 12 June 2003[§] | 3 years, 192 days | K. R. Narayanan |
| 10 | | Arvind Dave IPS (Retd) (born 1940) | Uttar Pradesh | 13 June 2003 | 5 August 2004 | 1 year, 53 days | A. P. J. Abdul Kalam |
| 11 | | Shivinder Singh Sidhu IAS (Retd) (1929–2018) | Punjab | 6 August 2004 | 22 July 2008[§] | 3 years, 351 days |
| 12 | | Gurbachan Jagat IPS (Retd) (born 1942) | Chandigarh | 23 July 2008 | 28 July 2013 | 5 years, 5 days | Pratibha Patil |
| 13 | | Ashwani Kumar IPS (Retd) (1950–2020) (Additional Charge) | Himachal Pradesh | 29 July 2013 | 30 December 2013 | 154 days | Pranab Mukherjee |
| 14 | | Vinod Kumar Duggal IAS (Retd) (born 1944) | Punjab | 31 December 2013 | 14 September 2014[‡] | 257 days |
| 15 | | Krishan Kant Paul IPS (Retd) (born 1948) (Additional Charge) | Chandigarh | 16 September 2014 | 15 May 2015 | 241 days |
| 16 | | Syed Ahmed (1943–2015) | Maharashtra | 16 May 2015 | 27 September 2015[†] | 134 days |
| 17 | | V. Shanmuganathan (born 1949) (Additional Charge) | Tamil Nadu | 30 September 2015 | 20 August 2016 | 325 days |
| 18 | | Najma Heptulla (born 1940) | Madhya Pradesh | 21 August 2016 | 1 May 2018 | 1 year, 253 days |
| 19 | | Jagdish Mukhi (born 1942) (Acting) | National Capital Territory of Delhi | 2 May 2018 | 30 May 2018 | 28 days | Ram Nath Kovind |
| (18) | | Najma Heptulla (born 1940) | Madhya Pradesh | 31 May 2018 | 26 June 2019 | 1 year, 26 days |
| 20 | | Padmanabha Balakrishna Acharya (1931–2023) (Acting) | Karnataka | 27 June 2019 | 22 July 2019 | 25 days |
| (18) | | Najma Heptulla (born 1940) | Madhya Pradesh | 23 July 2019 | 11 August 2021 | 2 years, 19 days |
| 21 | | Ganga Prasad Chaurasia (born 1939) (Additional Charge) | Bihar | 12 August 2021 | 26 August 2021 | 14 days |
| 22 | | La. Ganesan (1945–2025) | Tamil Nadu | 27 August 2021 | 21 February 2023[§] | 1 year, 178 days |
| 23 | | Anusuiya Uikey (born 1957) | Madhya Pradesh | 22 February 2023 | 29 July 2024 | 1 year, 158 days | Droupadi Murmu |
| 24 | | Lakshman Prasad Acharya (born 1954) (Additional Charge) | Uttar Pradesh | 31 July 2024 | 2 January 2025 | 155 days |
| 25 | | Ajay Kumar Bhalla IAS (Retd.) (born 1960) | Punjab | 3 January 2025 | Incumbent | 1 year, 137 days |