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Hydrogen

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Hydrogen

Hydrogen is a chemical element; it has the symbol H and atomic number 1. It is the lightest and most abundant chemical element in the universe, constituting about 75% of all normal matter. Under standard conditions, hydrogen is a gas of diatomic molecules with the formula H2, called dihydrogen, or sometimes hydrogen gas, molecular hydrogen, or simply hydrogen. Dihydrogen is colorless, odorless, non-toxic, and highly combustible. Stars, including the Sun, mainly consist of hydrogen in a plasma state, while on Earth, hydrogen is found as the gas H2 (dihydrogen) and in molecules, such as in water and organic compounds. The most common isotope of hydrogen, 1H, consists of one proton, one electron, and no neutrons. Hydrogen gas was first produced artificially in the 17th century by the reaction of acids with metals. Henry Cavendish, in 1766–1781, identified hydrogen gas as a distinct substance and discovered its property of producing water when burned: this is the origin of hydrogen's name, which means 'water-former' (from Ancient Greek: ὕδωρ, romanized: húdōr, lit. 'water', and γεννάω, gennáō, 'I bring forth'). Understanding the colors of light absorbed and emitted by hydrogen was a crucial part of the development of quantum mechanics. Hydrogen, typically nonmetallic except under extreme pressure, readily forms covalent bonds with most nonmetals, contributing to the formation of compounds like water and various organic substances. Its role is crucial in acid–base reactions, which mainly involve proton exchange among soluble molecules. In ionic compounds, hydrogen can take the form of either a negatively-charged anion, where it is known as hydride, or as a positively charged cation, H+, hydron. Although tightly bonded to water molecules, hydrons strongly affect the behavior of aqueous solutions, as reflected in the importance of pH. Hydride, on the other hand, is rarely observed because it tends to deprotonate solvents, yielding H2. In the early universe, neutral hydrogen atoms formed about 370,000 years after the Big Bang as the universe expanded and plasma had cooled enough for electrons to remain bound to protons. After stars began to form, most of the hydrogen in the intergalactic medium was re-ionized. Nearly all hydrogen production is done by transforming fossil fuels, particularly steam reforming of natural gas. It can also be produced from water or saline by electrolysis, but this process is more expensive. Its main industrial uses include fossil fuel processing and ammonia production for fertilizer. Emerging uses for hydrogen include the use of fuel cells to generate electricity.

Infobox

Appearance
Colorless gas
Atomic number (Z)
1
Group
group 1: hydrogen and alkali metals
Period
period 1
Block
s-block
Electron configuration
1s1
Electrons per shell
1
Phase at STP
gas
Melting point
(H2) 13 K (−259 °C, −434 °F)
Boiling point
(H2) 20 K (−252 °C, −423 °F)
Density (at STP)
0 g/L
when liquid (at m.p.)
0 g/cm3 (solid: 0 g/cm3)
when liquid (at b.p.)
0 g/cm3
Triple point
13 K, 7 kPa
Critical point
32 K, 1 MPa
Heat of fusion
(H2) 0 kJ/mol
Heat of vaporization
(H2) 0 kJ/mol
Molar heat capacity
14 J/(mol·K) (H) 28 J/(mol·K) (H2)
Specific heat capacity
14303 J/(kg·K) (H)
P (Pa)
Vapor pressure P (Pa) 1 10 100 1 k 10 k 100 k at T (K) 15 20
Oxidation states
common: −1, 1
Electronegativity
Pauling scale: 2
Ionization energies
1st: 1312 kJ/mol
Covalent radius
31±5 pm
Van der Waals radius
120 pm
Natural occurrence
primordial
Crystal structure
hexagonal (hP4)
Lattice constants
a = 378 pm c = 618 pm (at triple point)
Thermal conductivity
0 W/(m⋅K)
Magnetic ordering
diamagnetic
Molar magnetic susceptibility
−3 ×10−6 cm3/mol (298 K)
Speed of sound
1310 m/s (gas, 27 °C)
CAS Number
12385-13-6 1333-74-0 (H2)
Naming
name means 'water-former' in Greek
Discovery and first isolation
Henry Cavendish (1766)
Named by
Antoine Lavoisier (1783)
Main isotopes
Main isotopes Decay Isotope abun­dance half-life (t1/2) mode pro­duct 1H 99 % stable 2H 0 % stable 3H trace 12 y β− 3He Abundance of deuterium is highly variable
1H
99 %
2H
0 %
3H
trace

Tables

at T (K)
at T (K)
P (Pa)
at T (K)
10 k
15
100 k
20
P (Pa)
1
10
100
1 k
10 k
100 k
at T (K)
15
20
Isotope
Isotope
Main isotopes
Isotope
Main isotopes
abun­dance
Main isotopes
half-life (t1/2)
Decay
mode
Decay
pro­duct
1H
1H
Main isotopes
1H
Main isotopes
99 %
Main isotopes
stable
2H
2H
Main isotopes
2H
Main isotopes
0 %
Main isotopes
stable
3H
3H
Main isotopes
3H
Main isotopes
trace
Main isotopes
12 y
Decay
β−
Decay
3He
Main isotopes
Decay
Isotope
abun­dance
half-life (t1/2)
mode
pro­duct
1H
99 %
stable
2H
0 %
stable
3H
trace
12 y
β−
3He
Thermal and physical properties of hydrogen (H2) at atmospheric pressure · Properties › Dihydrogen › Thermal and physical properties
100
100
Temperature (K)
100
Density (kg/m3)
0
Specific heat (kJ/kg K)
11
Dynamic viscosity (kg/m s)
4
Kinematic viscosity (m2/s)
1
Thermal conductivity (W/m K)
6
Thermal diffusivity (m2/s)
2
Prandtl Number
0
150
150
Temperature (K)
150
Density (kg/m3)
0
Specific heat (kJ/kg K)
12
Dynamic viscosity (kg/m s)
5
Kinematic viscosity (m2/s)
3
Thermal conductivity (W/m K)
0
Thermal diffusivity (m2/s)
4
Prandtl Number
0
200
200
Temperature (K)
200
Density (kg/m3)
0
Specific heat (kJ/kg K)
13
Dynamic viscosity (kg/m s)
6
Kinematic viscosity (m2/s)
5
Thermal conductivity (W/m K)
0
Thermal diffusivity (m2/s)
7
Prandtl Number
0
250
250
Temperature (K)
250
Density (kg/m3)
0
Specific heat (kJ/kg K)
14
Dynamic viscosity (kg/m s)
7
Kinematic viscosity (m2/s)
8
Thermal conductivity (W/m K)
0
Thermal diffusivity (m2/s)
1
Prandtl Number
0
300
300
Temperature (K)
300
Density (kg/m3)
0
Specific heat (kJ/kg K)
14
Dynamic viscosity (kg/m s)
8
Kinematic viscosity (m2/s)
1
Thermal conductivity (W/m K)
0
Thermal diffusivity (m2/s)
1
Prandtl Number
0
350
350
Temperature (K)
350
Density (kg/m3)
0
Specific heat (kJ/kg K)
14
Dynamic viscosity (kg/m s)
9
Kinematic viscosity (m2/s)
1
Thermal conductivity (W/m K)
0
Thermal diffusivity (m2/s)
2
Prandtl Number
0
400
400
Temperature (K)
400
Density (kg/m3)
0
Specific heat (kJ/kg K)
14
Dynamic viscosity (kg/m s)
1
Kinematic viscosity (m2/s)
1
Thermal conductivity (W/m K)
0
Thermal diffusivity (m2/s)
2
Prandtl Number
0
450
450
Temperature (K)
450
Density (kg/m3)
0
Specific heat (kJ/kg K)
14
Dynamic viscosity (kg/m s)
1
Kinematic viscosity (m2/s)
2
Thermal conductivity (W/m K)
0
Thermal diffusivity (m2/s)
3
Prandtl Number
0
500
500
Temperature (K)
500
Density (kg/m3)
0
Specific heat (kJ/kg K)
14
Dynamic viscosity (kg/m s)
1
Kinematic viscosity (m2/s)
2
Thermal conductivity (W/m K)
0
Thermal diffusivity (m2/s)
3
Prandtl Number
0
550
550
Temperature (K)
550
Density (kg/m3)
0
Specific heat (kJ/kg K)
14
Dynamic viscosity (kg/m s)
1
Kinematic viscosity (m2/s)
3
Thermal conductivity (W/m K)
0
Thermal diffusivity (m2/s)
4
Prandtl Number
0
600
600
Temperature (K)
600
Density (kg/m3)
0
Specific heat (kJ/kg K)
14
Dynamic viscosity (kg/m s)
1
Kinematic viscosity (m2/s)
3
Thermal conductivity (W/m K)
0
Thermal diffusivity (m2/s)
5
Prandtl Number
0
700
700
Temperature (K)
700
Density (kg/m3)
0
Specific heat (kJ/kg K)
14
Dynamic viscosity (kg/m s)
1
Kinematic viscosity (m2/s)
4
Thermal conductivity (W/m K)
0
Thermal diffusivity (m2/s)
6
Prandtl Number
0
800
800
Temperature (K)
800
Density (kg/m3)
0
Specific heat (kJ/kg K)
14
Dynamic viscosity (kg/m s)
1
Kinematic viscosity (m2/s)
5
Thermal conductivity (W/m K)
0
Thermal diffusivity (m2/s)
8
Prandtl Number
0
900
900
Temperature (K)
900
Density (kg/m3)
0
Specific heat (kJ/kg K)
14
Dynamic viscosity (kg/m s)
1
Kinematic viscosity (m2/s)
6
Thermal conductivity (W/m K)
0
Thermal diffusivity (m2/s)
1
Prandtl Number
0
1000
1000
Temperature (K)
1000
Density (kg/m3)
0
Specific heat (kJ/kg K)
14
Dynamic viscosity (kg/m s)
2
Kinematic viscosity (m2/s)
8
Thermal conductivity (W/m K)
0
Thermal diffusivity (m2/s)
1
Prandtl Number
0
1100
1100
Temperature (K)
1100
Density (kg/m3)
0
Specific heat (kJ/kg K)
15
Dynamic viscosity (kg/m s)
2
Kinematic viscosity (m2/s)
9
Thermal conductivity (W/m K)
0
Thermal diffusivity (m2/s)
1
Prandtl Number
0
1200
1200
Temperature (K)
1200
Density (kg/m3)
0
Specific heat (kJ/kg K)
15
Dynamic viscosity (kg/m s)
2
Kinematic viscosity (m2/s)
1
Thermal conductivity (W/m K)
0
Thermal diffusivity (m2/s)
1
Prandtl Number
0
1300
1300
Temperature (K)
1300
Density (kg/m3)
0
Specific heat (kJ/kg K)
15
Dynamic viscosity (kg/m s)
2
Kinematic viscosity (m2/s)
1
Thermal conductivity (W/m K)
0
Thermal diffusivity (m2/s)
1
Prandtl Number
0
1400
1400
Temperature (K)
1400
Density (kg/m3)
0
Specific heat (kJ/kg K)
15
Dynamic viscosity (kg/m s)
2
Kinematic viscosity (m2/s)
1
Thermal conductivity (W/m K)
0
Thermal diffusivity (m2/s)
2
Prandtl Number
0
1500
1500
Temperature (K)
1500
Density (kg/m3)
0
Specific heat (kJ/kg K)
16
Dynamic viscosity (kg/m s)
2
Kinematic viscosity (m2/s)
1
Thermal conductivity (W/m K)
0
Thermal diffusivity (m2/s)
2
Prandtl Number
0
1600
1600
Temperature (K)
1600
Density (kg/m3)
0
Specific heat (kJ/kg K)
16
Dynamic viscosity (kg/m s)
2
Kinematic viscosity (m2/s)
1
Thermal conductivity (W/m K)
0
Thermal diffusivity (m2/s)
2
Prandtl Number
0
1700
1700
Temperature (K)
1700
Density (kg/m3)
0
Specific heat (kJ/kg K)
16
Dynamic viscosity (kg/m s)
2
Kinematic viscosity (m2/s)
1
Thermal conductivity (W/m K)
0
Thermal diffusivity (m2/s)
3
Prandtl Number
0
1800
1800
Temperature (K)
1800
Density (kg/m3)
0
Specific heat (kJ/kg K)
16
Dynamic viscosity (kg/m s)
2
Kinematic viscosity (m2/s)
2
Thermal conductivity (W/m K)
0
Thermal diffusivity (m2/s)
3
Prandtl Number
0
1900
1900
Temperature (K)
1900
Density (kg/m3)
0
Specific heat (kJ/kg K)
17
Dynamic viscosity (kg/m s)
3
Kinematic viscosity (m2/s)
2
Thermal conductivity (W/m K)
0
Thermal diffusivity (m2/s)
3
Prandtl Number
0
2000
2000
Temperature (K)
2000
Density (kg/m3)
0
Specific heat (kJ/kg K)
18
Dynamic viscosity (kg/m s)
3
Kinematic viscosity (m2/s)
2
Thermal conductivity (W/m K)
0
Thermal diffusivity (m2/s)
3
Prandtl Number
0
Temperature (K)
Density (kg/m3)
Specific heat (kJ/kg K)
Dynamic viscosity (kg/m s)
Kinematic viscosity (m2/s)
Thermal conductivity (W/m K)
Thermal diffusivity (m2/s)
Prandtl Number
100
0
11
4
1
6
2
0
150
0
12
5
3
0
4
0
200
0
13
6
5
0
7
0
250
0
14
7
8
0
1
0
300
0
14
8
1
0
1
0
350
0
14
9
1
0
2
0
400
0
14
1
1
0
2
0
450
0
14
1
2
0
3
0
500
0
14
1
2
0
3
0
550
0
14
1
3
0
4
0
600
0
14
1
3
0
5
0
700
0
14
1
4
0
6
0
800
0
14
1
5
0
8
0
900
0
14
1
6
0
1
0
1000
0
14
2
8
0
1
0
1100
0
15
2
9
0
1
0
1200
0
15
2
1
0
1
0
1300
0
15
2
1
0
1
0
1400
0
15
2
1
0
2
0
1500
0
16
2
1
0
2
0
1600
0
16
2
1
0
2
0
1700
0
16
2
1
0
3
0
1800
0
16
2
2
0
3
0
1900
0
17
3
2
0
3
0
2000
0
18
3
2
0
3
0

References

  1. "Standard Atomic Weights: Hydrogen"
    https://www.ciaaw.org/hydrogen.htm
  2. Pure and Applied Chemistry
    https://www.degruyter.com/document/doi/10.1515/pac-2019-0603/html
  3. Inorganic chemistry
    https://books.google.com/books?id=vEwj1WZKThEC&pg=PA240
  4. Selected Values of the Crystallographic Properties of Elements
  5. CRC Handbook of Chemistry and Physics
    https://web.archive.org/web/20110303222309/http://www-d0.fnal.gov/hardware/cal/lvps_info/engineering/elementmagn.pdf
  6. CRC, Handbook of Chemistry and Physics
  7. Foundations of Chemistry
    https://link.springer.com/article/10.1007/s10698-022-09448-5
  8. A Guide to the Elements
  9. Nature's Building Blocks
  10. Van Nostrand's Encyclopedia of Chemistry
  11. Chinese Physics C
    https://www-nds.iaea.org/amdc/ame2020/NUBASE2020.pdf
  12. Periodic table
    https://pse-info.de/en/element/H
  13. "Energy Levels"
    http://astro.unl.edu/naap/hydrogen/levels.html
  14. Wolfram Alpha
    http://www.wolframalpha.com/input/?i=photon+wavelength+13.6+ev
  15. Quantum chemistry
  16. The Feynman lectures on physics
    https://www.feynmanlectures.caltech.edu/III_12.html
  17. Journal of Physical and Chemical Reference Data
    https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9888147
  18. Pure Appl. Chem.
    http://www.iupac.org/publications/pac/1988/pdf/6007x1115.pdf
  19. Physics of Atomic Nuclei
    https://ui.adsabs.harvard.edu/abs/2005PAN....68..491G
  20. Physical Review Letters
    https://ui.adsabs.harvard.edu/abs/2003PhRvL..90h2501K
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