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Hydrogen

Updated: Wikipedia source

Hydrogen

Hydrogen is a chemical element; it has the symbol H and atomic number 1. It is the lightest and most abundant chemical element in the universe, constituting about 75% of all normal matter. Under standard conditions, hydrogen is a gas of diatomic molecules with the formula H2, called dihydrogen, or sometimes hydrogen gas, molecular hydrogen, or simply hydrogen. Dihydrogen is colorless, odorless, non-toxic, and highly combustible. Stars, including the Sun, mainly consist of hydrogen in a plasma state, while on Earth, hydrogen is found as the gas H2 (dihydrogen) and in molecules, such as in water and organic compounds. The most common isotope of hydrogen, 1H, consists of one proton, one electron, and no neutrons. Hydrogen gas was first produced artificially in the 17th century by the reaction of acids with metals. Henry Cavendish, in 1766–1781, identified hydrogen gas as a distinct substance and discovered its property of producing water when burned: this is the origin of hydrogen's name, which means 'water-former' (from Ancient Greek: ὕδωρ, romanized: húdōr, lit. 'water', and γεννάω, gennáō, 'I bring forth'). Understanding the colors of light absorbed and emitted by hydrogen was a crucial part of the development of quantum mechanics. Hydrogen, typically nonmetallic except under extreme pressure, readily forms covalent bonds with most nonmetals, contributing to the formation of compounds like water and various organic substances. Its role is crucial in acid–base reactions, which mainly involve proton exchange among soluble molecules. In ionic compounds, hydrogen can take the form of either a negatively-charged anion, where it is known as hydride, or as a positively-charged cation, H+, called a proton. Although tightly bonded to water molecules, protons strongly affect the behavior of aqueous solutions, as reflected in the importance of pH. Hydride, on the other hand, is rarely observed because it tends to deprotonate solvents, yielding H2. In the early universe, neutral hydrogen atoms formed about 370,000 years after the Big Bang as the universe expanded and plasma had cooled enough for electrons to remain bound to protons. After stars began to form, most of the hydrogen in the intergalactic medium was re-ionized. Nearly all hydrogen production is done by transforming fossil fuels, particularly steam reforming of natural gas. It can also be produced from water or saline by electrolysis, but this process is more expensive. Its main industrial uses include fossil fuel processing and ammonia production for fertilizer. Emerging uses for hydrogen include the use of fuel cells to generate electricity.

Infobox

Appearance
Colorless gas
Atomic number (Z)
1
Group
group 1: hydrogen and alkali metals
Period
period 1
Block
s-block
Electron configuration
1s1
Electrons per shell
1
Phase at STP
gas
Melting point
(.mw- H2) 13.99 K (−259.16 °C, −434.49 °F)
Boiling point
(H2) 20.271 K (−252.879 °C, −423.182 °F)
Density (at STP)
0.08988 g/L
when liquid (at m.p.)
0.07 g/cm3 (solid: 0.0763 g/cm3)
when liquid (at b.p.)
0.07099 g/cm3
Triple point
13.8033 K, 7.041 kPa
Critical point
32.938 K, 1.2858 MPa
Heat of fusion
(H2) 0.117 kJ/mol
Heat of vaporization
(H2) 0.904 kJ/mol
Molar heat capacity
(H2) 28.836 J/(mol·K)
P (Pa)
Vapor pressure P (Pa) 1 10 100 1 k 10 k 100 k at T (K) 15 20
Oxidation states
common: −1, 1
Electronegativity
Pauling scale: 2.20
Ionization energies
1st: 1312.0 kJ/mol
Covalent radius
31±5 pm
Van der Waals radius
120 pm
Natural occurrence
primordial
Crystal structure
hexagonal (hP4)
Lattice constants
a = 378.97 pmc = 618.31 pm (at triple point)
Thermal conductivity
0.1805 W/(m⋅K)
Magnetic ordering
diamagnetic
Molar magnetic susceptibility
−3.98×10−6 cm3/mol (298 K)
Speed of sound
1310 m/s (gas, 27 °C)
CAS Number
12385-13-6 1333-74-0 (H2)
Naming
name means 'water-former' in Greek
Discovery and first isolation
Henry Cavendish (1766)
Named by
Antoine Lavoisier (1783)
Main isotopes
mw- body Main isotopes Decay Isotope abun­dance half-life (t1/2) mode pro­duct 1H 99.9855% stable 2H 0.0115% stable 3H trace 12.32 y β− 3He Abundance of deuterium is highly variable
1H
99.9855%
2H
0.0115%
3H
trace

Tables

at T (K)
at T (K)
P (Pa)
at T (K)
10 k
15
100 k
20
P (Pa)
1
10
100
1 k
10 k
100 k
at T (K)
15
20
mw- Isotope
mw- Isotope
Main isotopes
mw- Isotope
Main isotopes
abun­dance
Main isotopes
half-life (t1/2)
Decay
mode
Decay
pro­duct
1H
1H
Main isotopes
1H
Main isotopes
99.9855%
Main isotopes
stable
2H
2H
Main isotopes
2H
Main isotopes
0.0115%
Main isotopes
stable
3H
3H
Main isotopes
3H
Main isotopes
trace
Main isotopes
12.32 y
Decay
β−
Decay
3He
Main isotopes
Decay
mw- Isotope
abun­dance
half-life (t1/2)
mode
pro­duct
1H
99.9855%
stable
2H
0.0115%
stable
3H
trace
12.32 y
β−
3He
Thermal and physical properties of hydrogen (H2) at atmospheric pressure[60][61] · Properties › Dihydrogen › Thermal and physical properties
100
100
Temperature (K)
100
Density (kg/m3)
0.24255
Specific heat (kJ/kg K)
11.23
Dynamic viscosity (kg/m s)
4.21E-06
Kinematic viscosity (m2/s)
1.74E-05
Thermal conductivity (W/m K)
6.70E-02
Thermal diffusivity (m2/s)
2.46E-05
Prandtl Number
0.707
150
150
Temperature (K)
150
Density (kg/m3)
0.16371
Specific heat (kJ/kg K)
12.602
Dynamic viscosity (kg/m s)
5.60E-06
Kinematic viscosity (m2/s)
3.42E-05
Thermal conductivity (W/m K)
0.0981
Thermal diffusivity (m2/s)
4.75E-05
Prandtl Number
0.718
200
200
Temperature (K)
200
Density (kg/m3)
0.1227
Specific heat (kJ/kg K)
13.54
Dynamic viscosity (kg/m s)
6.81E-06
Kinematic viscosity (m2/s)
5.55E-05
Thermal conductivity (W/m K)
0.1282
Thermal diffusivity (m2/s)
7.72E-05
Prandtl Number
0.719
250
250
Temperature (K)
250
Density (kg/m3)
0.09819
Specific heat (kJ/kg K)
14.059
Dynamic viscosity (kg/m s)
7.92E-06
Kinematic viscosity (m2/s)
8.06E-05
Thermal conductivity (W/m K)
0.1561
Thermal diffusivity (m2/s)
1.13E-04
Prandtl Number
0.713
300
300
Temperature (K)
300
Density (kg/m3)
0.08185
Specific heat (kJ/kg K)
14.314
Dynamic viscosity (kg/m s)
8.96E-06
Kinematic viscosity (m2/s)
1.10E-04
Thermal conductivity (W/m K)
0.182
Thermal diffusivity (m2/s)
1.55E-04
Prandtl Number
0.706
350
350
Temperature (K)
350
Density (kg/m3)
0.07016
Specific heat (kJ/kg K)
14.436
Dynamic viscosity (kg/m s)
9.95E-06
Kinematic viscosity (m2/s)
1.42E-04
Thermal conductivity (W/m K)
0.206
Thermal diffusivity (m2/s)
2.03E-04
Prandtl Number
0.697
400
400
Temperature (K)
400
Density (kg/m3)
0.06135
Specific heat (kJ/kg K)
14.491
Dynamic viscosity (kg/m s)
1.09E-05
Kinematic viscosity (m2/s)
1.77E-04
Thermal conductivity (W/m K)
0.228
Thermal diffusivity (m2/s)
2.57E-04
Prandtl Number
0.69
450
450
Temperature (K)
450
Density (kg/m3)
0.05462
Specific heat (kJ/kg K)
14.499
Dynamic viscosity (kg/m s)
1.18E-05
Kinematic viscosity (m2/s)
2.16E-04
Thermal conductivity (W/m K)
0.251
Thermal diffusivity (m2/s)
3.16E-04
Prandtl Number
0.682
500
500
Temperature (K)
500
Density (kg/m3)
0.04918
Specific heat (kJ/kg K)
14.507
Dynamic viscosity (kg/m s)
1.26E-05
Kinematic viscosity (m2/s)
2.57E-04
Thermal conductivity (W/m K)
0.272
Thermal diffusivity (m2/s)
3.82E-04
Prandtl Number
0.675
550
550
Temperature (K)
550
Density (kg/m3)
0.04469
Specific heat (kJ/kg K)
14.532
Dynamic viscosity (kg/m s)
1.35E-05
Kinematic viscosity (m2/s)
3.02E-04
Thermal conductivity (W/m K)
0.292
Thermal diffusivity (m2/s)
4.52E-04
Prandtl Number
0.668
600
600
Temperature (K)
600
Density (kg/m3)
0.04085
Specific heat (kJ/kg K)
14.537
Dynamic viscosity (kg/m s)
1.43E-05
Kinematic viscosity (m2/s)
3.50E-04
Thermal conductivity (W/m K)
0.315
Thermal diffusivity (m2/s)
5.31E-04
Prandtl Number
0.664
700
700
Temperature (K)
700
Density (kg/m3)
0.03492
Specific heat (kJ/kg K)
14.574
Dynamic viscosity (kg/m s)
1.59E-05
Kinematic viscosity (m2/s)
4.55E-04
Thermal conductivity (W/m K)
0.351
Thermal diffusivity (m2/s)
6.90E-04
Prandtl Number
0.659
800
800
Temperature (K)
800
Density (kg/m3)
0.0306
Specific heat (kJ/kg K)
14.675
Dynamic viscosity (kg/m s)
1.74E-05
Kinematic viscosity (m2/s)
5.69E-04
Thermal conductivity (W/m K)
0.384
Thermal diffusivity (m2/s)
8.56E-04
Prandtl Number
0.664
900
900
Temperature (K)
900
Density (kg/m3)
0.02723
Specific heat (kJ/kg K)
14.821
Dynamic viscosity (kg/m s)
1.88E-05
Kinematic viscosity (m2/s)
6.90E-04
Thermal conductivity (W/m K)
0.412
Thermal diffusivity (m2/s)
1.02E-03
Prandtl Number
0.676
1000
1000
Temperature (K)
1000
Density (kg/m3)
0.02424
Specific heat (kJ/kg K)
14.99
Dynamic viscosity (kg/m s)
2.01E-05
Kinematic viscosity (m2/s)
8.30E-04
Thermal conductivity (W/m K)
0.448
Thermal diffusivity (m2/s)
1.23E-03
Prandtl Number
0.673
1100
1100
Temperature (K)
1100
Density (kg/m3)
0.02204
Specific heat (kJ/kg K)
15.17
Dynamic viscosity (kg/m s)
2.13E-05
Kinematic viscosity (m2/s)
9.66E-04
Thermal conductivity (W/m K)
0.488
Thermal diffusivity (m2/s)
1.46E-03
Prandtl Number
0.662
1200
1200
Temperature (K)
1200
Density (kg/m3)
0.0202
Specific heat (kJ/kg K)
15.37
Dynamic viscosity (kg/m s)
2.26E-05
Kinematic viscosity (m2/s)
1.12E-03
Thermal conductivity (W/m K)
0.528
Thermal diffusivity (m2/s)
1.70E-03
Prandtl Number
0.659
1300
1300
Temperature (K)
1300
Density (kg/m3)
0.01865
Specific heat (kJ/kg K)
15.59
Dynamic viscosity (kg/m s)
2.39E-05
Kinematic viscosity (m2/s)
1.28E-03
Thermal conductivity (W/m K)
0.568
Thermal diffusivity (m2/s)
1.96E-03
Prandtl Number
0.655
1400
1400
Temperature (K)
1400
Density (kg/m3)
0.01732
Specific heat (kJ/kg K)
15.81
Dynamic viscosity (kg/m s)
2.51E-05
Kinematic viscosity (m2/s)
1.45E-03
Thermal conductivity (W/m K)
0.61
Thermal diffusivity (m2/s)
2.23E-03
Prandtl Number
0.65
1500
1500
Temperature (K)
1500
Density (kg/m3)
0.01616
Specific heat (kJ/kg K)
16.02
Dynamic viscosity (kg/m s)
2.63E-05
Kinematic viscosity (m2/s)
1.63E-03
Thermal conductivity (W/m K)
0.655
Thermal diffusivity (m2/s)
2.53E-03
Prandtl Number
0.643
1600
1600
Temperature (K)
1600
Density (kg/m3)
0.0152
Specific heat (kJ/kg K)
16.28
Dynamic viscosity (kg/m s)
2.74E-05
Kinematic viscosity (m2/s)
1.80E-03
Thermal conductivity (W/m K)
0.697
Thermal diffusivity (m2/s)
2.82E-03
Prandtl Number
0.639
1700
1700
Temperature (K)
1700
Density (kg/m3)
0.0143
Specific heat (kJ/kg K)
16.58
Dynamic viscosity (kg/m s)
2.85E-05
Kinematic viscosity (m2/s)
1.99E-03
Thermal conductivity (W/m K)
0.742
Thermal diffusivity (m2/s)
3.13E-03
Prandtl Number
0.637
1800
1800
Temperature (K)
1800
Density (kg/m3)
0.0135
Specific heat (kJ/kg K)
16.96
Dynamic viscosity (kg/m s)
2.96E-05
Kinematic viscosity (m2/s)
2.19E-03
Thermal conductivity (W/m K)
0.786
Thermal diffusivity (m2/s)
3.44E-03
Prandtl Number
0.639
1900
1900
Temperature (K)
1900
Density (kg/m3)
0.0128
Specific heat (kJ/kg K)
17.49
Dynamic viscosity (kg/m s)
3.07E-05
Kinematic viscosity (m2/s)
2.40E-03
Thermal conductivity (W/m K)
0.835
Thermal diffusivity (m2/s)
3.73E-03
Prandtl Number
0.643
2000
2000
Temperature (K)
2000
Density (kg/m3)
0.0121
Specific heat (kJ/kg K)
18.25
Dynamic viscosity (kg/m s)
3.18E-05
Kinematic viscosity (m2/s)
2.63E-03
Thermal conductivity (W/m K)
0.878
Thermal diffusivity (m2/s)
3.98E-03
Prandtl Number
0.661
Temperature (K)
Density (kg/m3)
Specific heat (kJ/kg K)
Dynamic viscosity (kg/m s)
Kinematic viscosity (m2/s)
Thermal conductivity (W/m K)
Thermal diffusivity (m2/s)
Prandtl Number
100
0.24255
11.23
4.21E-06
1.74E-05
6.70E-02
2.46E-05
0.707
150
0.16371
12.602
5.60E-06
3.42E-05
0.0981
4.75E-05
0.718
200
0.1227
13.54
6.81E-06
5.55E-05
0.1282
7.72E-05
0.719
250
0.09819
14.059
7.92E-06
8.06E-05
0.1561
1.13E-04
0.713
300
0.08185
14.314
8.96E-06
1.10E-04
0.182
1.55E-04
0.706
350
0.07016
14.436
9.95E-06
1.42E-04
0.206
2.03E-04
0.697
400
0.06135
14.491
1.09E-05
1.77E-04
0.228
2.57E-04
0.69
450
0.05462
14.499
1.18E-05
2.16E-04
0.251
3.16E-04
0.682
500
0.04918
14.507
1.26E-05
2.57E-04
0.272
3.82E-04
0.675
550
0.04469
14.532
1.35E-05
3.02E-04
0.292
4.52E-04
0.668
600
0.04085
14.537
1.43E-05
3.50E-04
0.315
5.31E-04
0.664
700
0.03492
14.574
1.59E-05
4.55E-04
0.351
6.90E-04
0.659
800
0.0306
14.675
1.74E-05
5.69E-04
0.384
8.56E-04
0.664
900
0.02723
14.821
1.88E-05
6.90E-04
0.412
1.02E-03
0.676
1000
0.02424
14.99
2.01E-05
8.30E-04
0.448
1.23E-03
0.673
1100
0.02204
15.17
2.13E-05
9.66E-04
0.488
1.46E-03
0.662
1200
0.0202
15.37
2.26E-05
1.12E-03
0.528
1.70E-03
0.659
1300
0.01865
15.59
2.39E-05
1.28E-03
0.568
1.96E-03
0.655
1400
0.01732
15.81
2.51E-05
1.45E-03
0.61
2.23E-03
0.65
1500
0.01616
16.02
2.63E-05
1.63E-03
0.655
2.53E-03
0.643
1600
0.0152
16.28
2.74E-05
1.80E-03
0.697
2.82E-03
0.639
1700
0.0143
16.58
2.85E-05
1.99E-03
0.742
3.13E-03
0.637
1800
0.0135
16.96
2.96E-05
2.19E-03
0.786
3.44E-03
0.639
1900
0.0128
17.49
3.07E-05
2.40E-03
0.835
3.73E-03
0.643
2000
0.0121
18.25
3.18E-05
2.63E-03
0.878
3.98E-03
0.661

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