| Portrait | Name(Birth–Death) | Term of office | Political party | Cabinet | Portfolio |
| Term | Time in office |
| 1 | | Franz Blücher(1896–1959) | 20 September 1949–29 October 1957 | 8 years, 30 days | FDP | Adenauer IAdenauer II | Marshall Plan/Economic Cooperation |
| 2 | | Ludwig Erhard(1897–1977) | 29 October 1957–16 October 1963 | 5 years, 362 days | CDU | Adenauer IIIAdenauer IV | Economic Affairs |
| 3 | | Erich Mende(1916–1998) | 17 October 1963–28 October 1966 | 3 years, 10 days | FDP | Erhard IErhard II | Intra-German Relations |
| The office was vacant from 28 October to 8 November 1966. |
| 4 | | Hans-Christoph Seebohm(1903–1967) | 8 November 1966–1 December 1966 | 23 days | CDU | Erhard II | Transport |
| 5 | | Willy Brandt(1913–1992) | 1 December 1966–22 October 1969 | 2 years, 325 days | SPD | Kiesinger | Foreign Affairs |
| 6 | | Walter Scheel(1919–2016) | 22 October 1969–16 May 1974 | 4 years, 207 days | FDP | Brandt IBrandt II | Foreign Affairs |
| 7 | | Hans-Dietrich Genscher(1927–2016)1st term | 17 May 1974–17 September 1982 | 8 years, 123 days | FDP | Schmidt ISchmidt IISchmidt III | Foreign Affairs |
| 8 | | Egon Franke(1913–1995) | 17 September 1982–1 October 1982 | 14 days | SPD | Schmidt III | Intra-German Relations |
| The office was vacant from 1 October to 4 October 1982. |
| 9 | | Hans-Dietrich Genscher(1927–2016)2nd term | 4 October 1982–18 May 1992 | 9 years, 230 days | FDP | Kohl IKohl IIKohl IIIKohl IV | Foreign Affairs |
| 10 | | Jürgen Möllemann(1945–2003) | 18 May 1992–21 January 1993 | 249 days | FDP | Kohl IV | Economic Affairs |
| 11 | | Klaus Kinkel(1936–2019) | 21 January 1993–27 October 1998 | 5 years, 279 days | FDP | Kohl IVKohl V | Foreign Affairs |
| 12 | | Joschka Fischer(b. 1948) | 27 October 1998–22 November 2005 | 7 years, 26 days | Alliance 90/The Greens | Schröder ISchröder II | Foreign Affairs |
| 13 | | Franz Müntefering(b. 1940) | 22 November 2005–21 November 2007 | 1 year, 364 days | SPD | Merkel I | Labour and Social Affairs |
| 14 | | Frank-Walter Steinmeier(b. 1956) | 21 November 2007–27 October 2009 | 1 year, 340 days | SPD | Merkel I | Foreign Affairs |
| 15 | | Guido Westerwelle(1961–2016) | 27 October 2009–16 May 2011 | 1 year, 201 days | FDP | Merkel II | Foreign Affairs |
| 16 | | Philipp Rösler(b. 1973) | 16 May 2011–17 December 2013 | 2 years, 215 days | FDP | Merkel II | Economic Affairs |
| 17 | | Sigmar Gabriel(b. 1959) | 17 December 2013–14 March 2018 | 4 years, 87 days | SPD | Merkel III | Economic Affairs (2013–2017)Foreign Affairs (2017–2018) |
| 18 | | Olaf Scholz(b. 1958) | 14 March 2018–8 December 2021 | 3 years, 269 days | SPD | Merkel IV | Finance |
| 19 | | Robert Habeck(b. 1969) | 8 December 2021–6 May 2025 | 3 years, 149 days | Alliance 90/The Greens | Scholz | Economic Affairs and Climate Protection |
| 20 | | Lars Klingbeil(b. 1978) | 6 May 2025–Incumbent | 219 days | SPD | Merz | Finance |