| Portrait | Name (Birth–Death) | Term of office | Political party | Cabinet | Portfolio |
| Term | Time in office |
| 1 | | Franz Blücher (1896–1959) | 20 September 1949 – 29 October 1957 | 8 years, 30 days | FDP | Adenauer I Adenauer II | Marshall Plan/Economic Cooperation |
| 2 | | Ludwig Erhard (1897–1977) | 29 October 1957 – 16 October 1963 | 5 years, 362 days | CDU | Adenauer III Adenauer IV | Economic Affairs |
| 3 | | Erich Mende (1916–1998) | 17 October 1963 – 28 October 1966 | 3 years, 10 days | FDP | Erhard I Erhard II | Intra-German Relations |
| The office was vacant from 28 October to 8 November 1966. |
| 4 | | Hans-Christoph Seebohm (1903–1967) | 8 November 1966 – 1 December 1966 | 23 days | CDU | Erhard II | Transport |
| 5 | | Willy Brandt (1913–1992) | 1 December 1966 – 22 October 1969 | 2 years, 325 days | SPD | Kiesinger | Foreign Affairs |
| 6 | | Walter Scheel (1919–2016) | 22 October 1969 – 16 May 1974 | 4 years, 207 days | FDP | Brandt I Brandt II | Foreign Affairs |
| 7 | | Hans-Dietrich Genscher (1927–2016) 1st term | 17 May 1974 – 17 September 1982 | 8 years, 123 days | FDP | Schmidt I Schmidt II Schmidt III | Foreign Affairs |
| 8 | | Egon Franke (1913–1995) | 17 September 1982 – 1 October 1982 | 14 days | SPD | Schmidt III | Intra-German Relations |
| The office was vacant from 1 October to 4 October 1982. |
| 9 | | Hans-Dietrich Genscher (1927–2016) 2nd term | 4 October 1982 – 18 May 1992 | 9 years, 230 days | FDP | Kohl I Kohl II Kohl III Kohl IV | Foreign Affairs |
| 10 | | Jürgen Möllemann (1945–2003) | 18 May 1992 – 21 January 1993 | 249 days | FDP | Kohl IV | Economic Affairs |
| 11 | | Klaus Kinkel (1936–2019) | 21 January 1993 – 27 October 1998 | 5 years, 279 days | FDP | Kohl IV Kohl V | Foreign Affairs |
| 12 | | Joschka Fischer (b. 1948) | 27 October 1998 – 22 November 2005 | 7 years, 26 days | Alliance 90/The Greens | Schröder I Schröder II | Foreign Affairs |
| 13 | | Franz Müntefering (b. 1940) | 22 November 2005 – 21 November 2007 | 1 year, 364 days | SPD | Merkel I | Labour and Social Affairs |
| 14 | | Frank-Walter Steinmeier (b. 1956) | 21 November 2007 – 27 October 2009 | 1 year, 340 days | SPD | Merkel I | Foreign Affairs |
| 15 | | Guido Westerwelle (1961–2016) | 27 October 2009 – 16 May 2011 | 1 year, 201 days | FDP | Merkel II | Foreign Affairs |
| 16 | | Philipp Rösler (b. 1973) | 16 May 2011 – 17 December 2013 | 2 years, 215 days | FDP | Merkel II | Economic Affairs |
| 17 | | Sigmar Gabriel (b. 1959) | 17 December 2013 – 14 March 2018 | 4 years, 87 days | SPD | Merkel III | Economic Affairs (2013–2017) Foreign Affairs (2017–2018) |
| 18 | | Olaf Scholz (b. 1958) | 14 March 2018 – 8 December 2021 | 3 years, 269 days | SPD | Merkel IV | Finance |
| 19 | | Robert Habeck (b. 1969) | 8 December 2021 – 6 May 2025 | 3 years, 149 days | Alliance 90/The Greens | Scholz | Economic Affairs and Climate Protection |
| 20 | | Lars Klingbeil (b. 1978) | 6 May 2025 – Incumbent | 1 year, 18 days | SPD | Merz | Finance |